課程資訊
課程名稱
聚烯烴科技
Polyolefin Science and Technology 
開課學期
110-1 
授課對象
工學院  化學工程學研究所  
授課教師
鄒海雄 
課號
ChemE5067 
課程識別碼
524 U2260 
班次
 
學分
3.0 
全/半年
半年 
必/選修
選修 
上課時間
星期四7,8,9(14:20~17:20) 
上課地點
綜302 
備註
化工選修課程。
總人數上限:50人
外系人數限制:5人 
Ceiba 課程網頁
http://ceiba.ntu.edu.tw/1101ChemE5067_pst 
課程簡介影片
 
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課程概述

Science and technology of polyolefins, most specifically polyolefins based on C2 to C5 olefins obtained from steam cracking. The course will cover olefin polymerization methods (radical, ionic, and metal-coordinated insertion) and kinetics (activation, initiation, propagation, termination, transfer, and mathematic approaches), homogeneous and heterogeneous catalyst technology (activator, initiator, support, electron donor, Ziegler-Natta, metallocene, and organometallic), polymerization reactor dynamics (CSTR and tubular, slurry, solution, gas-phase, and hybrid, reactor granule technology, heat and mass transfer), structural characterization (molecular weights, composition, rheology, and morphology), structure and property relationships (plastics, rubbers, tackifiers, crystallization, crosslinking, self-association, mechanisms and mechanics of plasticity, elasticity, and adhesion), and polyolefin blends and compounds (thermodynamics and dynamics of blends and compounds). 

課程目標
Polyolefins account for majority of plastics, synthetic thermoset rubbers, thermoplastic elastomers and tackifiers produced and are the backbone of polymer industries, both in Taiwan and globally. This course will prepare the students to work in the polymer industry or to continue to pursue research in polymers. This course will also teach the students to apply chemical engineering fundamentals, thermodynamics, kinetics, mechanics, engineering mathematics, catalysis science, reactor dynamics, materials and polymer science, to the science and technology of design, synthesis, and manufacturing of polyolefins. 
課程要求
Thermodynamics, Mass and Energy Balance, Organic Chemistry, Physical Chemistry (Frist two years of Chemical Engineering Required Classes) 
預期每週課後學習時數
 
Office Hours
每週四 17:20~18:20 備註: TA : 王聰偉 d10524007@ntu.edu.tw 02-33663067 化工一館307室 
指定閱讀
An English textbook written by me will be provided.
Individual class lecture notes (in Chinese) will be provided.
 
參考書目
L. H. Sperling, “Introduction to Physical Polymer Science”, 4th ed., 2006
J. B. P. Soares and T. F. L. McKenna, “Polyolefin Reaction Engineering”, 2012
M. Rubinstein and R. H. Colby, “Polymer Physics”, 2003
P. C. Hiemenz and T. P. Lodge, “Polymer Chemistry”, 2nd ed., 2007
W. W. Graessley, “Polymeric Liquids and Networks: Structure and Properties”, 2004
E. Piorkowska and G. C. Rutledge, “Handbook of Polymer Crystallization”, 2013
J. Scheirs and W. Kaminsky, “Metallocene-Based Polyolefins”, Vol. 1, 2000 
評量方式
(僅供參考)
 
No.
項目
百分比
說明
1. 
Homework 
20% 
 
2. 
Midterm 
35% 
 
3. 
Final 
45% 
 
 
課程進度
週次
日期
單元主題
第1週
9/23  Polyolefin structures and applications
 
第2週
9/30  Olefin polymerization kinetics
 
第3週
10/7  Olefin co-polymerization and branching kinetics

 
第4週
10/14  Initiators for radical and ionic polymerization of olefins
 
第5週
10/21  Organometallic catalysts for coordinative insertion polymerization of olefins 
第6週
10/28  Solution and bulk olefin polymerization reactors
 
第7週
11/4  Slurry and fluidized bed olefin polymerization reactors
 
第8週
11/11  期中考
 
第9週
11/18  Polyolefin structure and composition characterizations
 
第10週
11/25  Polyolefin rheology and morphology
 
第11週
12/2  Polyolefin crystallization
 
第12週
12/9  Structure-property relationship of polyolefin plastics and plastomers
 
第13週
12/16  Structure-property relationship of polyolefin rubbers, elastomers, and tackifiers
 
第14週
12/23  Thermodynamics of polyolefin blends
 
第15週
12/30  Morphology development in polyolefin blends
 
第16週
1/6  期末考
 
第17週
1/13  Reading assignment
 
第18週
1/20  Reading assignment